Delicate substituent effect of isophthalate tectons on the structural assembly of diverse 4-connected metal–organic frameworks (MOFs)Electronic supplementary information (ESI) available: Calculated and experimental X-ray powder diffraction (XRPD) patterns, additional structural illustrations, TGA curves, and solid-state emission spectra for 1–3. CCDC reference numbers 716142–716144. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b904977kCrystal datafor 1: C22H20.40N2O4.20Zn (Mr= 445.37), monoclinic, P21/n, a= 11.053(1), b= 11.376(1), c= 15.978(1) , β= 103.634(1)°, V= 1952.2(3) 3, Z= 4, ρ= 1.515 g cm−3, µ= 1.291 mm−1, S= 1.060, R= 0.0289 and wR= 0.0698. Crystal datafor 2: C44H44N4O12Zn2(Mr= 951.57), monoclinic, P21/n, a= 12.7027(8), b= 20.832(1), c= 16.958(1) , β= 102.889(1)°, V= 4374.3(5) 3, Z= 4, ρ= 1.445 g cm−3, µ= 1.163 mm−1, S= 1.017, R= 0.0321 and wR= 0.0784. Crystal datafor 3: C25H28N2O5Zn (Mr= 501.86), monoclinic, P21/n, a= 7.4048(7), b= 17.
In: CrystEngComm, Jg. 11 (2009-09-01), Heft 9, S. 1800-1802
Online
academicJournal
Zugriff:
Assembly of isophthalate derivatives with ZnIIin the presence of a flexible ligand 1,3-bis(4-pyridyl)propane yields distinct 4-connected coordination frameworks of sql(3.85)(32.83.9) and diatopologies, which reveal the delicate substituent effect of isophthalate tectons. The 3-D network in complex 2is of 4-fold interpenetration with a new topology, displaying a unique polyrotaxane and polycatenane character. [ABSTRACT FROM AUTHOR]
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Delicate substituent effect of isophthalate tectons on the structural assembly of diverse 4-connected metal–organic frameworks (MOFs)Electronic supplementary information (ESI) available: Calculated and experimental X-ray powder diffraction (XRPD) patterns, additional structural illustrations, TGA curves, and solid-state emission spectra for 1–3. CCDC reference numbers 716142–716144. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b904977kCrystal datafor 1: C22H20.40N2O4.20Zn (Mr= 445.37), monoclinic, P21/n, a= 11.053(1), b= 11.376(1), c= 15.978(1) , β= 103.634(1)°, V= 1952.2(3) 3, Z= 4, ρ= 1.515 g cm−3, µ= 1.291 mm−1, S= 1.060, R= 0.0289 and wR= 0.0698. Crystal datafor 2: C44H44N4O12Zn2(Mr= 951.57), monoclinic, P21/n, a= 12.7027(8), b= 20.832(1), c= 16.958(1) , β= 102.889(1)°, V= 4374.3(5) 3, Z= 4, ρ= 1.445 g cm−3, µ= 1.163 mm−1, S= 1.017, R= 0.0321 and wR= 0.0784. Crystal datafor 3: C25H28N2O5Zn (Mr= 501.86), monoclinic, P21/n, a= 7.4048(7), b= 17.
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| Autor/in / Beteiligte Person: | Ma, Lu-Fang ; Wang, Yao-Yu ; Liu, Jian-Qiang ; Yang, Guo-Ping ; Du, Miao ; Wang, Li-Ya |
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| Zeitschrift: | CrystEngComm, Jg. 11 (2009-09-01), Heft 9, S. 1800-1802 |
| Veröffentlichung: | 2009 |
| Medientyp: | academicJournal |
| ISSN: | 1466-8033 (print) |
| DOI: | 10.1039/b904977k |
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