1D → 1D Two-fold parallel interpenetrated coordination polymers with a bis(pyridylurea) ligandElectronic supplementary information (ESI) available: Experimental details: synthesis and characterization of the ligand L and compounds 1–4, and crystallographic data. CCDC reference numbers 739485–739488. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b922566hCrystal data for 1: C30H52CdCl2N12O12(956.14), colourless block, crystal system: orthorhombic, space group: Ibam, a= 14.1957(10), b= 15.7796 (11), c= 18.5297(12) Å, V= 4150.7(5) Å3, T= 173(2) K, Z= 4, Dc= 1.530 g cm−3, F000= 1976, μ= 0.726 mm−1, 13087 reflections collected, 1894 unique (Rint= 0.024), 1744 observed [I> 2σ(I)]; R1= 0.043, wR2= 0.121 [I> 2σ(I)].Crystal data for 2: C30H40CdN14O12(901.16), colourless block, crystal system: orthorhombic, space group: Ibam, a= 14.2829(14), b= 15.3547(15), c= 18.6193(18) Å, V= 4083.4(7) Å3, T= 173(2) K, Z= 4, Dc= 1.466 g cm−3, F000= 1848, μ= 0.609 mm−1, 140
In: CrystEngComm, Jg. 12 (2010-07-01), Heft 7, S. 2001-2004
Online
academicJournal
Zugriff:
Four unprecedented 1D → 1D interpenetrated (2,4) coordination polymers were obtained from a bis(4-pyridylurea) ligand and octahedral metal ions viacatenation of two parallel and collinear 1D ribbons of rings; the ligand L shows an ideal flexibility and adaptability in the formation of these structures. [ABSTRACT FROM AUTHOR]
Titel: |
1D → 1D Two-fold parallel interpenetrated coordination polymers with a bis(pyridylurea) ligandElectronic supplementary information (ESI) available: Experimental details: synthesis and characterization of the ligand L and compounds 1–4, and crystallographic data. CCDC reference numbers 739485–739488. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b922566hCrystal data for 1: C30H52CdCl2N12O12(956.14), colourless block, crystal system: orthorhombic, space group: Ibam, a= 14.1957(10), b= 15.7796 (11), c= 18.5297(12) Å, V= 4150.7(5) Å3, T= 173(2) K, Z= 4, Dc= 1.530 g cm−3, F000= 1976, μ= 0.726 mm−1, 13087 reflections collected, 1894 unique (Rint= 0.024), 1744 observed [I> 2σ(I)]; R1= 0.043, wR2= 0.121 [I> 2σ(I)].Crystal data for 2: C30H40CdN14O12(901.16), colourless block, crystal system: orthorhombic, space group: Ibam, a= 14.2829(14), b= 15.3547(15), c= 18.6193(18) Å, V= 4083.4(7) Å3, T= 173(2) K, Z= 4, Dc= 1.466 g cm−3, F000= 1848, μ= 0.609 mm−1, 140
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Autor/in / Beteiligte Person: | Li, Shaoguang ; Wu, Biao ; Hao, Yongjing ; Liu, Yanyan ; Yang, Xiao-Juan |
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Zeitschrift: | CrystEngComm, Jg. 12 (2010-07-01), Heft 7, S. 2001-2004 |
Veröffentlichung: | 2010 |
Medientyp: | academicJournal |
ISSN: | 1466-8033 (print) |
DOI: | 10.1039/b922566h |
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