Unprecedented magnetic relaxation via the fourth excited state in low-coordinate lanthanide single-ion magnets: a theoretical perspective.
In: Chemical Communications, Jg. 50 (2014-12-21), Heft 98, S. 15513-15516
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Zugriff:
Four low-coordinate SIMs have been studied to probe their relaxation dynamics using ab initio calculations. Our calculations reveal that both the symmetry and the equatorial ligand field play a key role in controlling the barrier heights in three-coordinate [Ln III (NSiMe 3 ) 3 ] complexes (Ln = Dy/Er). This study reveals an unprecedented blockade of magnetization up to three excited states for the Er(III) complex. [ABSTRACT FROM AUTHOR]
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| Titel: |
Unprecedented magnetic relaxation via the fourth excited state in low-coordinate lanthanide single-ion magnets: a theoretical perspective.
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| Autor/in / Beteiligte Person: | Singh, Saurabh Kumar ; Gupta, Tulika ; Shanmugam, Maheswaran ; Rajaraman, Gopalan |
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| Zeitschrift: | Chemical Communications, Jg. 50 (2014-12-21), Heft 98, S. 15513-15516 |
| Veröffentlichung: | 2014 |
| Medientyp: | academicJournal |
| ISSN: | 1359-7345 (print) |
| DOI: | 10.1039/c4cc05522e |
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