Higher spin states in some low-energy bis(tetramethyl-1,2-diaza-3,5-diborolyl) sandwich compounds of the first row transition metals: boraza analogues of the metallocenes.
In: New Journal of Chemistry, Jg. 43 (2019-03-21), Heft 11, S. 4497-4505
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Zugriff:
The known sandwich compound [η 5 -(CH 2 ) 3 N 2 (BPh) 2 CMe] 2 Fe in which adjacent C 2 units are replaced by isoelectronic BN units can be considered as a boraza analogues of ferrocene similar to borazine, B 3 N 3 H 6 , considered as a boraza analogue of benzene. In this connection, the related bis(1,2,3,5-tetramethyl-1,2-diaza-3,5-diborolyl) derivatives (Me 4 B 2 N 2 CH) 2 M (M = Ti, V, Cr, Mn, Fe, Co, Ni) for all of the first row transition metals have been optimized using density functional theory for comparison with the isoelectronic tetramethylcyclopentadienyl derivatives (Me 4 C 5 H) 2 M. Low-energy sandwich structures having parallel B 2 N 2 C rings in a trans orientation are found for all seven metals. The 1,2-diaza-3,5-diborolyl ligand appears to be a weaker field ligand than the isoelectronic cyclopentadienyl ligand as indicated by higher spin ground states for some (η 5 -Me 4 B 2 N 2 CH) 2 M sandwich compounds relative to the corresponding metallocenes (η 5 -Me 4 C 5 H) 2 M. Thus (η 5 -Me 4 B 2 N 2 CH) 2 Cr has a quintet ground state in contrast to the triplet ground state of (η 5 -Me 4 C 5 H) 2 Cr. Similarly, the sextet ground state of (η 5 -Me 4 B 2 N 2 CH) 2 Mn lies ∼18 kcal mol −1 below the quartet state in contrast to the doublet ground state of the isoelectronic (Me 4 C 5 H) 2 Mn. These sandwich compounds are potentially accessible by reaction of 1,2-diaza-3,5-diborolide anions with metal halides analogous to the synthesis of [η 5 -(CH 2 ) 3 N 2 (BPh) 2 CMe] 2 Fe. [ABSTRACT FROM AUTHOR]
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Titel: |
Higher spin states in some low-energy bis(tetramethyl-1,2-diaza-3,5-diborolyl) sandwich compounds of the first row transition metals: boraza analogues of the metallocenes.
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Autor/in / Beteiligte Person: | Chen, Jianlin ; Feng, Hao ; Xie, Yaoming ; King, R. Bruce ; Schaefer, Henry F. |
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Zeitschrift: | New Journal of Chemistry, Jg. 43 (2019-03-21), Heft 11, S. 4497-4505 |
Veröffentlichung: | 2019 |
Medientyp: | academicJournal |
ISSN: | 1144-0546 (print) |
DOI: | 10.1039/c8nj05517c |
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