“C–H…π Interaction” regulates the stereoselectivity in olefin polymerization.
In: Chemical Communications, Jg. 55 (2019-06-14), Heft 47, S. 6689-6692
Online
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Zugriff:
DFT calculations disclosed that the stereoselectivity of Sc-catalysed polymerization of halogenated styrenes could be co-regulated via C–H…π interactions between a coordinating THF and the phenyl ring of a monomer. Such a regulatory mechanism was theoretically confirmed by further studying the polymerization of various monomers, where the stereoselectivity could even shift from syndiotacticity to isotacticity. [ABSTRACT FROM AUTHOR]
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Titel: |
“C–H…π Interaction” regulates the stereoselectivity in olefin polymerization.
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Autor/in / Beteiligte Person: | Zhao, Yanan ; Luo, Gen ; Kang, Xiaohui ; Guo, Fang ; Zhu, Xuefeng ; Zheng, Rencheng ; Hou, Zhaomin ; Luo, Yi |
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Zeitschrift: | Chemical Communications, Jg. 55 (2019-06-14), Heft 47, S. 6689-6692 |
Veröffentlichung: | 2019 |
Medientyp: | academicJournal |
ISSN: | 1359-7345 (print) |
DOI: | 10.1039/c9cc02165e |
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