Chiral Au<subscript>22</subscript>(SR)<subscript>17</subscript><superscript>−</superscript>: a new ligand-binding strategy for structural prediction of thiolate-protected gold nanocluster.
In: Chemical Communications, Jg. 56 (2020-03-11), Heft 20, S. 2995-2998
Online
academicJournal
Zugriff:
A new atomic structure of chiral thiolate-protected gold nanocluster Au 22 (SR) 17 − is predicted on the basis of the new ligand-binding strategy, namely, redistributing the Au–S "staple" motifs on the well-known Au 10 core from previously laboratory-determined Au 21 (SR) 15 crystal structure. Density functional theory calculations show that this structure is very likely the realistic structure for the synthesized Au 22 (SR) 17 − . [ABSTRACT FROM AUTHOR]
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Titel: |
Chiral Au<subscript>22</subscript>(SR)<subscript>17</subscript><superscript>−</superscript>: a new ligand-binding strategy for structural prediction of thiolate-protected gold nanocluster.
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Autor/in / Beteiligte Person: | Xu, Wen Wu ; Lin, Dongdong ; Fu, Jie ; Zhao, Wenhui ; Duan, Xiangmei ; Zeng, Xiao Cheng |
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Zeitschrift: | Chemical Communications, Jg. 56 (2020-03-11), Heft 20, S. 2995-2998 |
Veröffentlichung: | 2020 |
Medientyp: | academicJournal |
ISSN: | 1359-7345 (print) |
DOI: | 10.1039/d0cc00134a |
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